JEE MAIN - Physics (2023 - 11th April Morning Shift - No. 2)
$$1 \mathrm{~kg}$$ of water at $$100^{\circ} \mathrm{C}$$ is converted into steam at $$100^{\circ} \mathrm{C}$$ by boiling at atmospheric pressure. The volume of water changes from $$1.00 \times 10^{-3} \mathrm{~m}^{3}$$ as a liquid to $$1.671 \mathrm{~m}^{3}$$ as steam. The change in internal energy of the system during the process will be
(Given latent heat of vaporisaiton $$=2257 \mathrm{~kJ} / \mathrm{kg}$$, Atmospheric pressure = $$\left.1 \times 10^{5} \mathrm{~Pa}\right)$$
説明
To find the change in internal energy, we need to consider both the heat added during the process and the work done during the process.
First, let's calculate the heat added ($Q$) to convert 1 kg of water at 100°C into steam at 100°C using the latent heat of vaporization:
$$Q = m \times L$$
where $$m = 1 \mathrm{~kg}$$ and $$L = 2257 \mathrm{~kJ/kg}$$:
$$Q = 1 \mathrm{~kg} \times 2257 \mathrm{~kJ/kg} = 2257 \mathrm{~kJ}$$
Next, let's calculate the work done ($W$) on the system during the process. The work done is given by:
$$W = -P \Delta V$$
where $$P$$ is the atmospheric pressure and $$\Delta V$$ is the change in volume. We are given that the atmospheric pressure is $$P = 1 \times 10^5 \mathrm{~Pa}$$, and the change in volume is
$$\Delta V = 1.671 \mathrm{~m}^3 - 1.00 \times 10^{-3} \mathrm{~m}^3 = 1.670 \mathrm{~m}^3$$.
Now, we can calculate the work done:
$$W = -(1 \times 10^5 \mathrm{~Pa})(1.670 \mathrm{~m}^3) = -167000 \mathrm{~J} = -167 \mathrm{~kJ}$$
Finally, we can find the change in internal energy ($\Delta U$) using the first law of thermodynamics:
$$\Delta U = Q + W$$
Substitute the values of $$Q$$ and $$W$$:
$$\Delta U = 2257 \mathrm{~kJ} - 167 \mathrm{~kJ} = 2090 \mathrm{~kJ}$$
The change in internal energy of the system during the process is +2090 kJ.
